From an agronomic point of view, I can think of a couple of advantages of ammonium sulfate (21-0-0-24S) when compared to ammonium thiosulfate solution (12-0-0-26S): The primary use of ammonium sulfate is in commercial pesticides and fertilizers. Thiosulfate leaching is an alkaline process (usually operated in the pH 8 to 10 range) so there are no concerns with corrosion of equipment in the recovery operation; The main chemical components of the thiosulfate leaching process (ammonium thiosulfate and ammonium sulphate) are common fertilizers. This chemical is incompatible with magnesium and aluminum powder. Ammonium thiosulfate (ATS) is commonly added to liquid nitrogen (N) solutions to provide sulfur (S) to crop plants. This substance dissolves rapidly in water, but not in alcohol and other synthetic mixtures, making it a solid addition for stabilizing fertilizers. (NTP, 1992). Sulfur response trials have shown ATS to be an effective S fertilizer, however, thiosulfate and its first breakdown product, tetrathionate, are not utilized by plants. AMMONIUM THIOSULFATE is sensitive to heat. Ammonium sulfate and ammonium thiosulfate, also known as ATS, are both very common nitrogen and sulfur sources in the dry and liquid fertilizer markets. Ammonium releases upon exposure to water and can make its way into the air in the form of ammonia gas. Mixtures with sodium chlorate can cause an exothermic reaction which can then decompose explosively.
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